Diethyl ether is produced from ethanol according to the following equation:

2CH3CH2OH(l) → CH3CH2OCH2CH3(l) + H2O(l)

What mass of ether will be produced is 207 g of ethanol reacts with a 66.7 percent yield?

Answers

Answer 1

The mass of ether produced is 111.5 g.

What is the mass produced?

Let us recall that a chemical reaction is said to have occurred when there is an interaction between reactants that leads to the formation of products. Usually, a given percentage of the reactants is always converted into products.

Now;

2[tex]CH_{3} CH_{2} OH[/tex](l) → [tex]CH_{3} CH_{2}OCH_{2}CH_{3}[/tex](l) + [tex]H_{2} O[/tex](l)

Number of moles of ethanol reacted = 207 g /46 g/mol

= 4.5 moles

If 2 mole of ethanol produced 1 mole of diethyl ether

4.5 moles of ethanol produced 4.5 moles *  1 mole/2 mole

= 2.25 moles

Theoretical yield of diethyl ether = 2.25 moles  * 74 g/mol = 166.5 g

We now have to find the actual yield hence;

66.7 = actual yield /166.5 * 100

actual yield  = 66.7 * 166.5/100

= 111.5 g

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Related Questions

What occurs when the air cools and begins to sink

Answers

Once hot air cools, it sinks to the earth's surface, here it is warmed by the ocean before rising back. This is known as a convection current.

Why convection current occurs?

Differential heating usually creates convection currents. Warmer (less dense) material rises, and cooler (more dense) material sinks.

The above movement is responsible for the formation of circulation patterns known as convection currents in the Earth's atmosphere, water, and mantle.

Convection currents in the Earth's mantle are thought to be the driving force behind tectonic plate movement.

Thus, convection current occurs when the air cools and begins to sink.

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You have a solution of 0.250 MNaCl. If you boil away 2/3 of the volume of water, what is the concentration of this solution

Answers

The concentration of this solution is 1.506 mole

The concentration of a solution is a measure of the amount of solute that has been dissolved in a given amount of solvent or solution.

Here given data is a solution of 0.250 M NaCl. If you boil away 2/3 of the volume of water  

We have to calculate concentration of this solution = ?

2/3 of the volume of water is 2/3×0.250 = 0.1666

Concentration = mass of solute dissolved/volume

Concentration = 0.250 M/0.1666

Concentration = 1.506mole

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What is the mass number for a carbon atom that contains 6 neutrons?

Answers

The mass number for a carbon atom which contains 6 neutrons is 12.

Which organelle in a cell contains DNA (genetic information)?

(A) mitochondrion

(B) ribosome

(C) chloroplast

(D) nucleus

Answers

Answer:

the answer is d the nucleus

Explanation:

the nucleus is like in the middle of a cell and I think is the most important.

hope this helps :)

A 4g book a 7kg lamp both in the living room

Answers

The distance between them is 2.5 m.

What is the distance of separation?

Now we know that the Newton's law of gravity said that the gravitational force of attraction between two objects is directly proportional to the product masses of the objects and inversely proportional to the distance of separation.

Now, given that;

F = Gm1m2/r^2

F = gravitational force

G = gravitational constant

m1 = mass of the book

m2 = mass of the lamp

r = distance of separation

r = √ Gm1m2//F

r =  √6.67 * 10^-11 * 4 * 7/2.99 10^-10

r =2.5 m

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Missing parts;

A 4 kg book and a 7 kg lamp are both in the living room. If the force of gravity between them is 2.99 10-10 N, how far apart are they?

what is electrophoresis ?...

Answers

Electrophoresis can be defined as a molecular biology procedure to separate biomolecules depending on the weight and electrical charges.

What is Electrophoresis?

Electrophoresis is a molecular biology procedure in which biomolecules such as DNA or proteins can be separated by their electrical charges and weight. For example, DNA has a negative charge thereby it migrates to the positive pole under an electrophoretic field and different DNA molecules can also be separated by their weight in base pairs.

In conclusion, electrophoresis is a technique used in molecular biology laboratories to separate biomolecules depending on the weight and electrical charges.

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What is the product of radioactive decay %e called?
• A. A gamma wave
• B. Nuclear fission
. c.
An alpha particle
• D.
A beta particle

Answers

Answer:

alpha particle

Explanation:

I'm pretty sure it's supposed to be "daughter", but I see that it's not a choice so my second best choice would be alpha particle

Classify the following materials as: pure substance (element or compound) or mixture (heterogeneous or homogeneous) NO. MATERIALS 1. ALUMINUM FOIL 2. AIR 3. SOIL 4. WATER 5. BRONZE 6. ACETIC ACID 7. PENCIL LEAD 8. BLOOD 9. IRON FILINGS 10. GASOLINE Pure Substance or Mixture? Element or Compound Homogeneous or Heterogeneous​

Answers

A sample of matter with both a definite and unchanging composition and specific chemical properties is referred to as a pure material.

A mixture is a substance comprised of two or more dissimilar chemicals that are not chemically linked.

Classify the following materials as: pure substance (element or compound) or mixture (heterogeneous or homogeneous) .

Materials

Aluminum Foil - Homogeneous MixtureAir - Heterogeneous MixtureSoil - Heterogeneous MixtureWATER - CompoundBRONZE - Homogeneous MixtureACETIC ACID - Homogeneous MixturePENCIL LEAD - ElementBLOOD - Heterogeneous MixtureIRON FILINGS - ElementGASOLINE - Homogeneous Mixture

Pure substances and mixtures are the two broad categories into which matter can be divided. A sort of matter known as a pure substance has qualities and a steady composition throughout the sample. Physically combining two or more elements and/or compounds results in a mixture. The two types of mixtures are homogeneous and heterogeneous. Pure substances include both elements and compounds. Substances made up of multiple atom types are known as compounds. The simplest compounds are called elements because they only contain one kind of atom.

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There are numerous starting points that a composer could use when writing a piece of music.
A. True
B. False, dynamics and tempo are the only starting points
C. False, composers never us a starting point
D. False, structure is the only starting point

Answers

It's true that there may be numerous starting points that a composer could use when writing a piece of music.

The composer may moreover start at a one-of-a-kind figure depending on the thoughts they've at that minute in time. In other expressions, it may be said that a vocalist or a guitarist is alluded to as a performer for that tally number. A composer is that as it may be an individual who sets a track to a song. Musical composition can talk about a unique piece or work of the track, both vocal or instrumental, the structure of a melodic piece, or the strategy of making or composing an unused piece of music. individuals who make modern compositions are alluded to as composers.

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How many quarts are equal to 5 pounds of Ethanol? The density of Ethanol is 0.789 g/mL

Answers

The volume of the ethanol in quarts is determined as 3.04 quarts.

Mass of the ethanol

The mass of the ethanol is calculated as follows;

volume of the ethanol = mass of the ethanol / density of the ethanol

mass of the ethanol in grams;

5 pounds = 2267.96 g

volume of the ethanol in milliliter (mL);

volume of the ethanol = (2267.96 g) / (0.789 g/mL)

volume of the ethanol = 2,874.47 mL

volume of the ethanol in quarts

1 mL = 0.00105669 quart

2,874.47 mL = ?

=  2,874.47 mL x 0.00105669 quart/mL

= 3.04 quarts

Thus, the volume of the ethanol in quarts is determined as 3.04 quarts.

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In general, what dose a subscript (such as the “2” in H2) tell about the molecule?

Answers

how many there are of each element for example H20 is 2 hydrogen atoms plus 1 oxygen atom

A scientist is observing a rare monkey in the jungle, and the monkey begins exhibiting an odd behavior. The scientist thinks this behavior may not have been observed in this species before, but he is not certain. The scientist records video of the behavior and takes many detailed notes.

The scientist becomes very excited about his finding and plans to share it with other scientists. The best way for him to communicate and defend his finding would be to
A.
immediately write a report claiming a newly discovered behavior, and then check later to see if others have observed it before.

B.
confirm that the behavior has not been observed before, and then present his finding in a report.

C.
defend his finding as a new discovery, even if another scientist has already published a report about the behavior.

D.
wait until other scientists ask him about his trip to the jungle, and then tell them about his finding.

Answers

B, you want to confirm a behavior has not been observed and then present it

If 2.25 g of orange mercury oxide decomposes to 2.09 g of liquid mercury and oxygen gas, what is the mass of oxygen produced?
Express your answer to two significant figures and include the appropriate units.


nothing
nothing

Answers

The mass, in grams, of oxygen that will be produced from the reaction to two significant figures, will be 0.17 grams.

Stoichiometric problems

Mercury oxide decomposes to liquid mercury and oxygen gas. The equation for the decomposition reaction is represented below:

[tex]2HgO + heat --- > 2Hg + O_2[/tex]

Mole of 2.25 g mercury oxide = mass/ molar mass

                = 2.25/216.59

                       = 0.0104 moles

Mole ratio of mercury oxide that decomposes and oxygen gas produced = 2:1.

Equivalent moles of oxygen gas produced = 0.0104/2

                                 = 0.0052 moles

Mass of 0.0052 moles oxygen gas = mole x molar mass

                                 = 0.0052 x 32

                                         = 0.1664 grams

To 2 significant figures, the amount of oxygen gas produced is 0.17 grams.

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Is hydrogen explosive? if so what makes it explosive?
please explaen
25 points

Answers

Hydrogen is explosive, because when it is exposed to air, it reacts with oxygen, releasing heat and forms either water or hydrogen peroxide.

What is hydrogen?

Hydrogen is the chemical element with the symbol H and atomic number    of  one (1).

Is hydrogen explosive?

Yes hydrogen is explosive. When hydrogen mixes with oxygen in the air, it forms an explosive mixture.

When molecular hydrogen and oxygen are combined and allowed to react together, energy is released and the molecules of hydrogen and oxygen can combine to form either water or hydrogen peroxide.

The reaction equation is given as;

H₂ + O₂ →  H₂O₂ + heat

This reaction is exothermic because it releases large amount of heat to the surrounding.

Thus, hydrogen is explosive, because when it is exposed to air, it reacts with oxygen, releasing heat and forms either water or hydrogen peroxide.

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How are elements organized in the periodic table?
A. By decreasing abundance
OB. By decreasing reactivity
OC. By increasing atomic number
OD. By increasing atomic mass

Answers

The elements are organized in the periodic table By increasing the atomic number.

The periodic desk is organized into companies' vertical columns, intervals horizontal rows, and families organizations of factors that might be similar. factors in the identical institution have the same range of valence electrons. Dmitri Mendeleev created the periodic desk by using arranging his factors in order of growing atomic mass. He determined that when they have been organized in this manner they form a repeating sample that is periodically repeated every seven factors.

The chemical factors are organized so as of increasing atomic range. The horizontal rows are called intervals and the vertical columns are called agencies. factors within the equal institution have comparable chemical houses. this is due to the fact they have an identical range of outer electrons and identical valency. The vertical columns on the periodic desk are referred to as corporations or families due to their comparable chemical behavior. all of the participants of a family of elements have an equal number of valence electrons and similar chemical homes.

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While at a crime scene, the forensic scientist sees a tiny hair on the floor next to the murder weapon. What should they do with this evidence?

A.
Collect the hair, and place it in a bag.

B.
Leave it there because it is so small.

C.
Dust it to the side so it’s out of the way.

D.
Take a photo of it, and then throw it away.

Answers

The forensic scientist  should collect the hair and place it in a bag as an evidence.

How does a hair help in crime study?

Hair analysis  is used as a tool widely for locating suspects in crime investigations.The hair possesses different characteristics which can be studied under a microscope which help in revealing a person's race, gender and color.

Considering if a person is poisoned, hair analysis can help in identifying the presence of poison in a the body.Although carrying out a blood test  after a certain period of time to detect presence of poison will give a negative result but hair analysis would not,it would definitely reveal the body being poisoned.

Hair samples collected along with hair follicles remaining intact are useful for DNA testing.This is because every cell has a nucleus  and is made up of chromosomes.The hair follicles contain DNA which provides useful information.

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Provide at least three reasons why studying the periodic trends of elements is important towards
having a good understanding of chemistry

Answers

The reasons that studying the periodic trends of elements is important towards having a good understanding of chemistry as the periodic table contain full information regarding an element. The second reason is that it gives brief knowledge about increasing and decreasing of atomic number as well mass of the elements. The third reason is that it shows metals as well as non metals separately.

What is periodic table?

Periodic table is defined as a table consist of chemical elements contains a series of atomic number generally in rows due to the reason that elements possesses same atomic number lie in the vertical columns.

Therefore, The reasons that studying the periodic trends of elements is important towards having a good understanding of chemistry as the periodic table contain full information regarding an element. The second reason is that it gives brief knowledge about increasing and decreasing of atomic number as well mass of the elements. The third reason is that it shows metals as well as non metals separately.

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What is the molarity of a solution that contains 5.00 moles of solute and 25.00 Liters of solution?

Select one:
a.0.20 M
b.0.89 M
c.0.25 M
d.3.20 M

Answers

Answer:

0.20

Explanation:

Molarity= no of moles/volume in litre

=5/25

= 0.20M

Sofia is a medical examiner who is performing an autopsy on a murder victim. What will this process MOST likely involve?

A.
She will look for trace evidence present on the body.

B.
She will donate the victim’s organs.

C.
She will prepare the victim’s body for burial.

D.
She will cremate the body.

Answers

A. She will look for trace evidence present on the body.

100 Points! Question in photo

Answers

The limiting reactant of the reaction will be aluminum (Al).

What are limiting reactants?

In chemical reactions, limiting reactants are reactants that are available in limited quantity. Thus, these reactant determines how much of the products are formed. Other reactants in the same reaction are said to be in excess.

From the equation of the reaction:

[tex]2Al + 2KOH + 6HOH --- > 2 KAl (OH)_4 + 3H_2[/tex]

The mole ratio of Al to KOH to HOH is 2:2:6 or 1:1:3.

Mole of 3.0 g Al = 3/27

                           = 0.111 moles

Mole of 15 mL, 8 M KOH = 8 x 15/1000

                                   = 0.12 moles

Mole of 75 mL of distilled water = 75/18

                                             = 4.167 moles

From the above number of moles of each reactant and the mole ratio, it is obvious that Al with 0.111 moles is the limiting reactant.

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Answer:

4.0 grams?

Explanation:

I DONT KNOW IF I AM RIGHT but if i am i wish u luck <3

hope i helped

Urgent 45 pts

Answer the next five questions based on the diagram:

How many electrons are in the n = 1 shell?

How many electrons are in the n = 2 shell?

How many electrons are needed to complete the n = 2 shell?

How many electrons are being shared between the two nitrogen atoms?

How many bonds exist between the two nitrogen atoms?

Answers

Answer:

When n = 1 then it means the first shell of an atom whereas n = 2 means the second shell of an atom and so on.

Explanation:

When n = 1 then it means the first shell of an atom whereas n = 2 means the second shell of an atom and so on.

As every atom consists of three sub-atomic particles which are protons, neutrons, and electrons.

Protons and neutrons reside inside the nucleus of an atom and electrons revolve outside the nucleus of the atom.

A covalent bond is defined as the bond formed by sharing of electrons between the two combining atoms.

Therefore, the given questions are answered as follows.

There are 2 electrons in the n = 1 shell.

There are 5 electrons in its n = 2 shell.

There are 5 electrons in nitrogen's outer shell before sharing electrons.

6 electrons are being shared between the two nitrogen atoms.

Covalent bonds exist between the two nitrogen atoms.

Explanation:

1. In the 1 shell there are 2 electrons

2. in the second shell there are 5 electrons

3. To complete the 2 shell are needed 3 electrons

4. Each of them share 3 elections

5. 3 bonds exist between the two nitrogen atoms

A student isolates 1.685 grams of iron (II) oxalate, FeC2O4. What is this amount in moles?

Answers

The amount in moles of iron (II) oxalate that has a mass of 1.685 grams is 0.01170mol.

How to convert mass to moles?

The number of moles in a substance can be calculated by dividing the mass of the substance by the molar mass.

According to this question, a student isolates 1.685 grams of iron (II) oxalate (FeC₂O₄).

Molar mass of FeC₂O₄ = 56 + 12(2) + 16(4) = 144g/mol

no of moles = 1.685g ÷ 144g/mol = 0.01170mol

Therefore, the amount in moles of iron (II) oxalate that has a mass of 1.685 grams is 0.01170mol.

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The police chief has reported that the evidence from the crime scene has been contaminated. What MOST likely happened in this scenario?

A.
The evidence was collected properly and brought to the lab.

B.
Outside materials were mixed in with collected evidence.

C.
The crime scene was preserved exactly as it was found.

D.
The local court accepted this evidence at a criminal trial.

Answers

The MOST likely happened in a situation where the police chief has reported that the evidence from the crime scene has been contaminated is the fact that outside materials were mixed in with collected evidence (Option B).

What does the crime scene mean?

The expression crime scene refers to all evidence found in a given place after a crime, which is fundamental to solving this type of police case.

In conclusion, the MOST likely happened in a situation where the police chief has reported that the evidence from the crime scene has been contaminated is the fact that outside materials were mixed in with collected evidence (Option B).

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Barnacles need a solid structure in the water to attach to and live on, which they can find on a turtle shell. The turtle is unaffected by the presence of the barnacles. That type of relationship bests describes what these two animals have?

Answers

the relationship between turtles and barnacles is an example of

co-evolution, where each species is continually adapting to changes with  the other.

Barnacles attaches to  turtle's shell due to its hardness. Barnacles needs  a hard surface to bind with so that it can thrive. A single barnacle doesn’t harm a turtle. But excessive barnacles can make a turtle inactive,also impact its vision and make it difficult to eat, and sometimes lead to infection.

.The cyprid larvae of barnacle has a special attachment devices which allow it to hold onto the substrate, e.g. cup-shaped attachment organs on the antennae. Once barnacle is settled, the barnacle develops into an adult and attaches in different  ways as gripping the skin, cementing to the shell or boring into it.

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If a normal dose CT scan delivers 700 mrem of radiation, how many CT scans would a
patient have to have to feel mild radiation sickness (50 rem)? Please help

Answers

The number of CT scans that a patient will have to undergo in order to feel mild radiation sickness would be 72 CT scans

Dimensional analysis

The normal dose CT scan delivers 700 mrem.

700 mrem = 700 x [tex]10^{-3}[/tex] rem

700 x [tex]10^{-3}[/tex] rem is equivalent to 0.7 rem.

In order for a patient to feel mild radiation sickness, 50 rem is needed.

If 1 CT scan is equivalent to 0.7 rem, then how many CT scans will give 50 rem?

           = 50 x 1/0.7

                    = 71.429 scans

Since CT scans cannot be a fraction, we then need to approximate to the nearest whole number.

Thus, a total of 72 CT scans will be required for a patient to have a feeling of radiation sickness.

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Scientific equation of how many gallons is in 1 liter?

Answers

Answer:

1 liter = 0.264172 us gallon

Explanation:

What is the density of sulfuric acid if the mass of the acid is 6.514 x 10¹ g and the volume
is 3.54x 10¹ mL?

Answers

The density of the sulfuric acid is 1.840 g/ml.

Given,

Mass of sulfuric acid = 6.514 × 10 g

Volume of sulfuric acid = 3.54 × 10 ml

We have to find the density of the sulfuric acid.

The density of any substance is defined as the mass per unit volume of the substance. Or, it is the ratio of mass to volume. The units of density are kg/m³, g/ml, or g/cm³.

It is given by the formula:

Density = Mass/ volume

Density = 6.514 × 10 g/ 3.54 × 10 ml

Density = 1.840 g/ml

Hence, the density of sulfuric acid is 1.840 g/ml

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A solution of sodium hydroxide was titrated against a solution of sulfuric acid. How many moles of sodium hydroxide would react with 1 mole of sulfuric acid? (Hint: It may help to write out a balanced symbol equation for the reaction. The chemical formulas of the acid and alkali are shown below.)

Answers

2 moles of sodium hydroxide are required to react with 1 mole of sulfuric acid.

What is stoichiometry?

Stoichiometry refers to the relation which exists between quantities of reactant and products.It is based on the law of conservation of mass where the mass of the reactants is equal to the mass of the products.Conclusion which can be made by this statement is that reactants and products form a ratio of positive integers.

Considering the reaction between sodium hydroxide and sulfuric acid given in the question number of moles of sodium hydroxide can be found out that are required to react with 1 mole of sulfuric acid using stoichiometry concept.

H₂SO₄+2 NaOH[tex]\rightarrow[/tex]Na₂SO₄+ 2 H₂O

From the reaction it is clear that 1 mole of sulfuric acid reacts with 2 moles of sodium hydroxide

Therefore,1 mole of sulfuric acid would react with

1×2/1=2 moles of sodium hydroxide.

Thus, 2 moles of sodium hydroxide react with 1 mole of sulfuric acid.

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Which property is least helpful in identifying a sample of matter
A.Reactivity
B. Boiling point
C. Melting point
D. Volume

Answers

The property which is least helpful in identifying a sample of matter is option D. Volume.

Property including melting factor, boiling factor, density, solubility, color, odor, and so on. is bodily houses. residences that describe how a substance modifications identity to produce a new substance are chemical houses.

The reactivity of a substance is a chemical property as opposed to physical assets. The purpose qualifies as a chemical property as it is predicated on its electron configuration to decide how it's going to behave around different substances.

A matter is an attribute of depending this is unbiased its chemical composition. Density, color, hardness, melting and boiling points and electric conductivity are all examples of physical properties.

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Answer: D Volume

Explanation:

Which element has an outer energy level that is almost full of electrons? O radium O carbon O krypton O iodine​

Answers

Explanation:

Hi, I think the answers Iodine.

hope it helps

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Suppose the magnitude of an electric field that exerts a 4. 80 x 10-17 n force on an electron is 300 n/c. What magnitude of the force does this field exert on a proton?. PLEASE HELPA weatherwoman is on the news explaining that there will be high winds on the central coast coming in from the ocean. Using Bernoulli's principle, what do we know about the ocean and the coast?A. The air over the ocean has more volume than the air over the coastB. The air over the ocean has more mass than the air over the coastC. There is less air pressure over the ocean than over the coastD. The air over the ocean has less mass than the air over the coastE. There is more air pressure over the ocean than over the coastF. The air over the ocean has less volume than the air over the coast which of the following best describes "totalitarianism"?A. Open electionsB. Political equalityC. Strong dictatorshipD. Classless society An archer stands at rest on a frictionless frozen lake; his total mass including his bow and quiver of arrows is 60.00 kg. He then fires a 0.030kg arrow at 50.0 m/s at an angle of 30.0 above the horizontal. If it takes 650N of force to break the ice and the arrow leaves the bow in 10ms, what force does the archer exert on the ice? FAST!!!!!!!!!!!plss HELPPPP(Did you know that chickens sometimes eat vegetables and fruits? A farmer likes to give the chickens apples to share. The farmer observes that 5 chickens eat 8 apples. What is the ratio of the number of chickens to apples?) a3:8 b5:8 c8:3 d8:5 Simplify the expression. negative 17 plus the quantity negative 2 and three tenths plus 8 and 12 hundredths end quantity divided by 6 all times 4 squared minus 8 and 6 tenths List three changes that occur in society when shifting from nomadic to agrarian. In a lab, a substance was heated by 6 Celsius each hour for 42 hours. 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What personal skills (like patience, perseverance, or humility) does a musician need in order to master the basics of music? How could these skills be used in other areas of life? A local clothing store has several standing orders with a supplier. The store receives new clothes on this schedule:a shipment of sweaters every 5 days,a shipment of jeans every 6 days,a shipment of dresses every 8 days, anda shipment of shoes every 12 days.The store received shipments of all four items today. Which of these are true? Select ALL that apply.A.The next time the clothing store will receive shipments of both jeans and sweaters is in 11 days. B.The next time the clothing store will receive shipments of both jeans and dresses is in 24 days. C.The next time the clothing store will receive shipments of both sweaters and dresses is in 40 days.D.The next time the clothing store will receive shipments of jeans, sweaters, and dresses is in 60 days.E.The next time the clothing store will receive shipments of both shoes and jeans is in 18 days. Name two Presidents who made use of "indirect sanctions": Simplify each expression. -5(1+2 i)+3 i(3-4 i) NEED HELP FOR RIGHT NOW PLEASE Hurry and help , there is only five minutes left 100+ points and brainly Which of the following characteristics best describe the properties of liquids? Select all that apply. A. Not easily compressed B. Easily compressed into a smaller volume C. Takes the shape of its container D. Has indefinite shape and fixed volume E. Has definite shape and volume F. Particles are packed tightly together, often in an orderly arrangement G. Expands to fill any volume Write the equation in slope-intercept form. Write the numbers in the equation as simplified proper fractions, improper fractions, or integers. Which of the following do the monotheistic religions have in common? aFollowers should not eat pork. bSacraments are used in worship. cSundays are devoted to worship. dFollowers honor the Ten Commandments. And please show the work plsss help When incorporated into a polypeptide chain not at the n or c terminus, _______ would make the charge of the polypeptide more positive.